Reaction mechanism of regioisomerization in binuclear (diaminocarbene)PdII complexes
نویسندگان
چکیده
منابع مشابه
synthesis of binuclear platinum complexes containing biphosphine ligand
هدف از این مطالعه طراحی یک روش کلی برای سنتز یک سری از کمپلکس های دو هسته ای متقارن سیکلومتاله شده پلاتین (ii) بوده که دارای یک لیگاند پل زن(1,2-bis[bis(pentafluoro-phenyl)phosphino]ethane),dfppe, است. از واکنش cis-[pt(r)2(sme2)2]، که در آنr= para-tolyl ، با یک اکی والان از لیگاند benzo[h]quinoline,bhq، در استون محصول [pt(r)(bhq)(sme2)] که در آن r= para-tolyl بدست می آید. همچنین از واکنش 5/0 اک...
Determination of Reaction Kinetic Parameters from Variable Temperature Kinetic Study for Oxidative Addition Reaction on Binuclear Cyclometalated Platinum(II) Complexes
The pseudo-first order rate constants and activation parameters have been determined using two methods, constant-temperature kinetic (CTK) and variable temperature kinetic (VTK), for the oxidative addition reactions of [Pt2Me2(C^N)2(µ-dppf)], (1a, C^N = deprotonated 2-phenylpyridine (ppy); 1b, C^N = deprotonated benzo[h]quinoline (bhq)) with MeI. The results obtained from VTK method are in agre...
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A systematic study has been undertaken to determine how local distortions affect the overall (molecular) magnetic anisotropies in binuclear complexes. For this purpose we have applied a series of distortions to two binuclear Ni(II) model complexes and extracted the magnetic anisotropy parameters of multispin and giant-spin model Hamiltonians. Furthermore, local and molecular magnetic axes frame...
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ژورنال
عنوان ژورنال: Inorganica Chimica Acta
سال: 2021
ISSN: 0020-1693
DOI: 10.1016/j.ica.2020.120012